Steam Superheater:
Example 3.6: Oil (C12H26) is burned
with 20% excess air. Completely
combusted gases enter a steam superheater at 1550 °F
and exit at 1150 °F.
Steam enters at 400 psi and is 92% saturated. It is required to generate superheated steam at a temperature of
650 °F. Assume that there is no pressure drop in the
superheater and specific heat of the product gases is 0.25 Btu/(lb·°F). Determine the amount of steam that could be
produced per lb of oil burned.
Molecular weight of oil = 170.
Combustion of oil proceeds as follows:
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Solution
Basis: 1 lbmole of oil:
C
CO2 produced = 12 lbmol =
528 lb
C
H2O produced = 13 lbmol =
234 lb
C
O2 required (stoichiometric)
= 18.5 lbmol
C
O2 in the product =
0.2(18.5)(32) = 118.4 lb
C
N2 in the product =
3.764(1.2)(18.5) = 83.56 lbmol = 2340 lb
C
Mass of the gas per lb of oil, W:
W
= (528 + 234 + 118.4 + 2340)/170 = 18.942 lb
C
Sensible heat given by product gases to
wet steam, Qh:
Qh
= WCp(T1 - T2)
= 18.942(0.25)(2010 - 1610) = 1894 Btu
C
Heat absorbed by steam, qc:
qc
= 1335.9 - (424.2 + 0.92(780.4)) = 193.732 Btu/lb
C
Amount of steam produced per lb of oil
burned, wsteam:
wsteam
= Qh/qc
= 1894/193.732 = 9.777 lb